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Paper 2 Chemical Systems Section

Chemical Industries
Chloroalkali industry
(soap, PVC, etc.)

  • Given diagrams of the membrane cell used industrially to produce chlorine electrolytically
    » Explain the process using half reactions and the overall redox reaction taking place in the cells
    » Identify all the products and give a use of each
    » Make clear the meaning of the term electrolytic cell
    » Identify the cathode (reduction, H2) and the anode (oxidation, Cl2)
    » Describe the function of the cell membrane where applicable (ion exchange)
  • Identify the benefits to humankind of the products of this process
  • Identify risks associated with operating this cell
  • Given a flow diagram of, for example, the membrane cell (or even an unknown process pertinent to the manufacture of these products), be able to answer questions on aspects of the process.
  • For example identify the reactants and products of a particular step, or the purpose of a sequence of steps

Fertiliser Industry
(N, P, K)

  • List for plants:
    » three essential nutrients and their source:
    (C, H and O)
    (atmosphere CO2 and rain)
    » three primary nutrients and their source
    (N, P, K)
    (the soil)
  • Explain the function of N,P and K in plants
  • List for humans the four major elements, and their source, on which the body relies for form and function
    »(C, H, O and N)
    » atmosphere, water and food, animals and plants
  • Match the parts of the human body that utilise particular chemical elements with those from a list of primary, secondary and micronutrients in plants
    » (eg. P, K, Fe, Ca, ...)
  • Give the form in which plants and animals absorb N, P and K
    » eg. nitrates, phosphates, potassium salts,,...
    » implies the need to fix nitrogen
  • Give the source of:
    » N (guano)
    » P (bone meal)
    » K (German mines)
    before and after the First World War
  • Interpret the N:P:K fertilizer ratio
  • Describe and explain (rates, yield, neutralisation, ...) using chemical equations wherever appropriate, these aspects of the industrial manufacture of fertilizers,, given diagrams, flow charts, and so on:
    » N2-fractional distillation of air
    » H2-at SASOL from coal and steam
    » NH3-Haber Process
    » HNO3-Ostwald Process
    » H2SO4-Contact Process
  • Give sources of potash (mined imported potassium salts like KNO3, K2SO4, KNO3...)
  • Describe the term eutrophication and:
    » What causes it
    » Its consequences
    » Identify circumstances that can lead to it from a supplied text
    » Suggest ways to prevent it
    » Suggest ways to solve the problems that arise from it
  • Evaluate the use of inorganic fertilisers on humans and the environment

Batteries, torch, car, etc

  • Use the knowledge gained studying galvanic cells to provide, for an unknown cell:
    » the equation for the cell reaction given the half equations
    » the cell voltage if applied with the voltage of the half cells
  • Explain and use the concepts:
    Energy stored in cells and batteries W = Vq
    Cell capacity and use the unit Amp-hour (Ah and mAh) and the equation:
    q = IΔt
    Primary cells and Secondary cells