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Paper 2 Chemical Systems Section
Chemical Industries
Chloroalkali industry
(soap, PVC, etc.)
- Given diagrams of the membrane cell used industrially to produce chlorine electrolytically
» Explain the process using half reactions and the overall redox reaction taking place in the cells
» Identify all the products and give a use of each
» Make clear the meaning of the term electrolytic cell
» Identify the cathode (reduction, H2) and the anode (oxidation, Cl2)
» Describe the function of the cell membrane where applicable (ion exchange)
- Identify the benefits to humankind of the products of this process
- Identify risks associated with operating this cell
- Given a flow diagram of, for example, the membrane cell
(or even an unknown process pertinent to the manufacture of these products), be able to answer questions
on aspects of the process.
- For example identify the reactants and products of a particular step, or the purpose of a sequence of steps
Fertiliser Industry
(N, P, K)
- List for plants:
» three essential nutrients and their source:
(C, H and O)
(atmosphere CO2 and rain)
» three primary nutrients and their source
(N, P, K)
(the soil)
- Explain the function of N,P and K in plants
- List for humans the four major elements, and their source, on which the body relies for form and function
»(C, H, O and N)
» atmosphere, water and food, animals and plants
- Match the parts of the human body that utilise particular chemical elements with those from a list of primary, secondary and micronutrients in plants
» (eg. P, K, Fe, Ca, ...)
- Give the form in which plants and animals absorb N, P and K
» eg. nitrates, phosphates, potassium salts,,...
» implies the need to fix nitrogen
- Give the source of:
» N (guano)
» P (bone meal)
» K (German mines)
before and after the First World War
- Interpret the N:P:K fertilizer ratio
- Describe and explain (rates, yield, neutralisation, ...) using chemical equations
wherever appropriate, these aspects of the industrial manufacture of fertilizers,, given diagrams, flow charts, and so on:
» N2-fractional distillation of air
» H2-at SASOL from coal and steam
» NH3-Haber Process
» HNO3-Ostwald Process
» H2SO4-Contact Process
- Give sources of potash (mined imported potassium salts like KNO3, K2SO4, KNO3...)
- Describe the term eutrophication and:
» What causes it
» Its consequences
» Identify circumstances that can lead to it from a supplied text
» Suggest ways to prevent it
» Suggest ways to solve the problems that arise from it
- Evaluate the use of inorganic fertilisers on humans and the environment
Batteries, torch, car, etc
- Use the knowledge gained studying galvanic cells to provide, for an unknown cell:
» the equation for the cell reaction given the half equations
» the cell voltage if applied with the voltage of the half cells
- Explain and use the concepts:
Energy stored in cells and batteries W = Vq
Cell capacity and use the unit Amp-hour (Ah and mAh) and the equation:
q = IΔt
Primary cells and Secondary cells
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